Stefania Chieppa defeated Natalie Piquion 6-2 6-1 in the Lecce 25K round of 16 on clay. The upset overturned the form book — Natalie Piquion came in leading the head-to-head 1–0, but Stefania Chieppa had been the form player, winning 5 of their last 9 on clay. Stefania Chieppa claimed a first win over Natalie Piquion in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2007-09-24 | Ciampino 10K | R32 | clay | Natalie Piquion | 7-5 6-2 |