Diana Brunel defeated Gracia Radovanovic 6-3 6-4 in the Montpellier 10K round of 32 on clay. The upset overturned the form book — Gracia Radovanovic came in leading the head-to-head 1–0, but Diana Brunel had been the form player, winning 3 of their last 7 on clay. Diana Brunel claimed a first win over Gracia Radovanovic in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-06-19 | Montpellier 10K | QF | clay | Gracia Radovanovic | 6-2 6-3 |