Valentina Sulpizio defeated Astrid Besser 6-4 6-1 in the RomeCanottieri 10K round of 32 on clay. The upset overturned the form book — Astrid Besser came in leading the head-to-head 1–0. Valentina Sulpizio claimed a first win over Astrid Besser in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-03-20 | RomeParioli 10K | R32 | clay | Astrid Besser | 6-3 2-6 6-2 |