Ismar Gorcic defeated Alessandro Da Col 6-3 1-6 6-3 in the Italy 4 3 round of 32 on clay. The upset overturned the form book — Alessandro Da Col came in leading the head-to-head 1–0. Ismar Gorcic claimed a first win over Alessandro Da Col in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-05-22 | Bosnia & Herzegovina F2 | R32 | clay | Alessandro Da Col | 6-2 7-5 |