Ana Timotic defeated Capucine Rousseau 6-1 6-4 in the Mont De Marsan 25K round of 32 on clay. The upset overturned the form book — Capucine Rousseau came in leading the head-to-head 1–0, but Ana Timotic had been the form player, winning 4 of their last 5 on clay. Ana Timotic claimed a first win over Capucine Rousseau in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-05-24 | Roland Garros | Q128 | clay | Capucine Rousseau | 6-4 3-6 6-1 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.