Angeles Montolio defeated Anabel Medina Garrigues 6-4 6-2 in the Madrid semi-final on clay. The result followed the form book — Angeles Montolio came in leading the head-to-head 3–1, defending last year's quarter-final. Angeles Montolio extended the head-to-head to 4–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2000-06-12 | Marseille 50K | F | clay | Angeles Montolio | 6-2 6-7(4) 6-4 |
| 1999-03-29 | Pontevedra 10K | F | hard | Anabel Medina Garrigues | 6-1 6-2 |
| 1999-02-08 | Mallorca 10K | QF | clay | Angeles Montolio | 6-3 6-4 |
| 1998-09-28 | Lerida 10K | R16 | clay | Angeles Montolio | 2-6 6-3 6-1 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.