Angel Jose Martin defeated Carlos Rexach Itoiz 5-3 4-1 5-4 in the Spain F8 qualifying round on clay. The upset overturned the form book — Carlos Rexach Itoiz came in leading the head-to-head 1–0. Angel Jose Martin claimed a first win over Carlos Rexach Itoiz in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2001-07-09 | Spain F1 | R32 | clay | Carlos Rexach Itoiz | 6-2 6-1 |