Marina Escobar Martinez defeated Ana Martin Ramirez 6-1 6-4 in the Girona 10K round of 32 on clay. The upset overturned the form book — Ana Martin Ramirez came in leading the head-to-head 1–0. Marina Escobar Martinez claimed a first win over Ana Martin Ramirez in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2001-09-24 | Lleida 10K | R32 | clay | Ana Martin Ramirez | 7-6(5) 6-2 |