Dominique Monami defeated Anne Gaelle Sidot 4-6 6-4 6-4 in the Luxembourg round of 16 on hard. The upset overturned the form book — Anne Gaelle Sidot came in defending last year's round of 32, but Dominique Monami had been the form player, winning 2 of their last 4 on hard. Dominique Monami extended the head-to-head to 2–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 1999-11-01 | Leipzig | R16 | carpet | Anne Gaelle Sidot | 3-6 6-2 6-3 |
| 1996-09-23 | Limoges 75K | QF | hard | Dominique Monami | 6-1 6-2 |