Carlos Martinez Comet defeated Quino Munoz 6-3 2-6 6-3 in the Spain F9 round of 32 on clay. The upset overturned the form book — Quino Munoz came in leading the head-to-head 3–0. Carlos Martinez Comet claimed a first win over Quino Munoz in four meetings, narrowing the head-to-head to 3–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 1999-10-15 | Spain 7 Masters 2 | QF | clay | Quino Munoz | 6-3 6-3 |
| 1997-01-03 | Spain 1 Masters 3 | R32 | clay | Quino Munoz | 6-0 6-4 |
| 1996-01-05 | Portugal 1 Masters 4 | R32 | clay | Quino Munoz | 6-1 6-2 |