Marc Marco Ripoll defeated Angel Jose Martin 6-4 5-7 6-4 in the Spain F6 round of 32 on clay. The upset overturned the form book — Angel Jose Martin came in leading the head-to-head 2–0. Marc Marco Ripoll claimed a first win over Angel Jose Martin in three meetings, narrowing the head-to-head to 2–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2000-08-14 | Spain F6 | R32 | clay | Angel Jose Martin | 1-4 5-4(1) 5-3 4-2 |
| 1999-10-15 | Spain 7 Masters 3 | QF | clay | Angel Jose Martin | 6-4 6-4 |